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N-Acetyl-1,3-phenylenediamine

N-Acetyl-1,3-phenylenediamine - Names and IdentifiersNameN-Acetyl-1,3-phenylenediamineSynonymsN

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N-Acetyl-1,3-phenylenediamine - Names and Identifiers

AdıN-Acetyl-1,3-phenylenediamine
EşanlamlarNSC 165576
CCRIS 4574
BRN 0775952
EINECS 203-021-5
3-aminoacetanilid
3-Aminoacetanilid
m-acetaminoaniline
M-Acetaminoaniline
m-Aminoacetanilide
3'-Aminoacetanilide
3'-amino-acetanilid
M-Amino acetanilide
3-Acetylaminoaniline
3-acetylaminoaniline
m-(Acetylamino)aniline
Acetanilide, 3'-amino-
3-Amino-N-acetylaniline
n-acetyl-m-fenylendiamin
N-Acetyl-m-fenylendiamin
3-Aminoacetanilid [Czech]
Acetyl-m-phenylenediamine
N-(3-Aminophenyl)acetamide
n-(3-aminophenyl)-acetamid
N-ACETYL-M-PHENYLENEDIAMINE
N-Acetyl-m-phenylenediamine
Acetamide, N-(3-aminophenyl)-
N-Acetyl-1,3-phenylenediamine
1-Amino-3-(acetylamino)benzene
N-Acetyl-m-fenylendiamin [Czech]
CAS'ın102-28-3
EINECS'in203-021-5
InChI'ninInChI=1/C8H10N2O/c1-6(11)10-8-4-2-3-7(9)5-8/h2-5H,9H2,1H3,(H,10,11)
InChIKeyPEMGGJDINLGTON-UHFFFAOYSA-N

N-Acetyl-1,3-phenylenediamine - Physico-chemical Properties

Moleküler FormülC8H10N2O
Molar Kütlesi150.18
Yoğunluk1.1392 (rough estimate)
Erime noktası86-88°C(lit.)
Boling Point271.72°C (rough estimate)
Flash Point189°C
Su Solubility1-5 g/100 mL at 24 ºC
Buhar Basıncı2.96E-06mmHg at 25°C
GörüntüRenkli kristal
RenkWhite to Gray to Brown
pKa14.82±0.70(Predicted)
Depolama KoşullarıKaranlık bir yerde saklayın, inert atmosfer, oda sıcaklığı
Kırılma Endeksi1.6180 (estimate)
MDL'ninMFCD00025229
Fiziksel ve Kimyasal ÖzelliklerCharacter: colorless needle crystal or platelet crystal.
melting point 87~89 ℃
soluble in cold water, ethanol, acetone, slightly soluble in benzene.
KullanımMainly used as intermediates for reactive dyes and disperse dyes

N-Acetyl-1,3-phenylenediamine - Risk and Safety

Tehlike SimbolleriXi - Kızdırıcı

Risk Kodları36/37/38 - Gözleri, solunum sistemini ve cildi rahatsız edici.
Güvenlik AçıklamasıS26 - Gözlerle temas halinde hemen bol miktarda suyla durulayın ve tıbbi tavsiye alın.
S36 - Uygun koruyucu giysiler giyin.
S37/39 Uygun eldiven ve göz/yüz koruması giyin
WGK Almanya3
RTECSAD8050000
TSCA'nınEvet.
HS Kodu29214200
Tehlike SınıfıIRRITANT

N-Acetyl-1,3-phenylenediamine - Upstream Downstream Industry

Zehirli Materiyaler3-Nitroaniline
Acetic acid
m-Phenylenediamine
3-Nitroaniline
Calcium sulfide

N-Acetyl-1,3-phenylenediamine - Nature

colorless needle crystals or platelets. Melting Point: 87-89 °c. Soluble in cold water, ethanol, acetone, benzene-soluble.

N-Acetyl-1,3-phenylenediamine - Preparation Method

M-phenylenediamine was dissolved in water. Hydrochloric acid was gradually added to form M-phenylenediamine hydrochloride. Then acetic anhydride is used for acylation, and the reaction product is neutralized to obtain the finished product.

N-Acetyl-1,3-phenylenediamine - Use

It is mainly used as an intermediate for reactive dyes such as reactive yellow and disperse dyes.

N-Acetyl-1,3-phenylenediamine - Safety

  • toxic, its toxicity can be found in M-phenylenediamine (C283). In addition to absorption through the skin can also be caused by inhalation of dust poisoning. Attention should be paid to dust prevention in the production process, and the site should be well ventilated. The operator should wear protective gear.
  • the use of fiberboard barrel liner plastic bag packaging, net weight 25kg per barrel. Store in a dry, ventilated place to avoid sun exposure. Handle with care and protection against moisture and heat. According to the provisions of toxic substances storage and transportation.

N-Acetyl-1,3-phenylenediamine - Reference Information

EPA kimyasal bilgileriTarafından sağlanan bilgiler: ofmpub.epa.gov (dış bağlantı)
Kullanım Mainly used as an intermediate for reactive dyes and disperse dyes
Dye intermediates. Mainly used for preparing reactive yellow K-RN and disperse dyes.
Üretim yöntemi is obtained by acylation of m-phenylenediamine. Add water and m-phenylenediamine to the reaction pot to dissolve. Add 30% hydrochloric acid, stir for half an hour, then add acetic acid, control the reaction temperature at 40 ℃, keep warm and stir for 1h, add refined salt for salting out, and filter. After neutralization, m-aminoacetanilide is obtained. Acylation operations may also use acetic anhydride as a raw material. Raw material consumption quota m-phenylenediamine 1021kg/t, acetic anhydride 1013kg/t, hydrochloric acid 475kg/t.
Kategorizehirli maddeler
zehirli klasifikasyonzehirlenmek
akūt toksik vein-mouse LD50: 320 mg/kg
stimülasyon verileri eyes-rabbit 500 mg/24 hours severe
yanılabilirlik tehlike özellikleri combustible; combustion produces toxic nitrogen oxide smoke
depolama ve taşıma özellikleridepo ventilasyonu ve düşük sıcaklık suyu
Ateş söndürme ajanı dry powder, foam, sand, carbon dioxide, mist water

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