4-Dimethylaminobenzaldehyde - Names and IdentifiersName4-DimethylaminobenzaldehydeSynonymsEhrli
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Adı | 4-Dimethylaminobenzaldehyde |
Eşanlamlar | Ehrlichs ERLICH'S REAGENT EHRLICH'S REAGENT EHRLICH'S REAGENT SICC HYDRAZINE METER SOLUTION DIMETHYLAMINOBENZALDEHYDE 4-Dimethylaminobenzaldehyde p-Dimethylaminobenzaldehyde P-(Dimethylamino)benzaldehyde 4-dimethyl amino benzaldehyde 4-amino-2,3-dimethylbenzaldehyde N,N-dimethyl-4-amino benzaldehyde 4-(N,N-Dimethyl)aminobenzaldehyde P-dimethylaminobenzaldehyde test solution(ChP) 4-(Dimethylamino)benzaldehyde test solution(ChP) |
CAS'ın | 100-10-7 |
EINECS'in | 202-819-0 |
InChI'nin | InChI=1/C9H11NO/c1-6-7(2)9(10)4-3-8(6)5-11/h3-5H,10H2,1-2H3 |
InChIKey | BGNGWHSBYQYVRX-UHFFFAOYSA-N |
Moleküler Formül | C9H11NO |
Molar Kütlesi | 149.19 |
Yoğunluk | 1.10g/mLat 20°C |
Erime noktası | 72-75°C(lit.) |
Boling Point | 176-177 °C (17 mmHg) |
Flash Point | 164 °C |
Su Solubility | 0.3 g/L (20 ºC) |
Çözünürlük | Soluble in alcohol, ether, acetone, chloroform and acetic acid, slightly soluble in water. |
Görüntü | White or pale yellow leafy crystals or powder |
Renk | White to pale yellow |
Odor | Characteristic odor |
Merck'ın | 14,3230 |
BRN | 606802 |
pKa | pK1:1.647(+1) (25°C) |
Depolama Koşulları | 2-8 ° C |
Kararlılık | Stable, but light sensitive. Incompatible with bases, strong oxidizing agents. |
Hassas | Hava duygusu |
Kırılma Endeksi | n20/D 1.417 |
MDL'nin | MFCD00003381 |
Fiziksel ve Kimyasal Özellikler | White or yellowish leaf-like crystals or powder. Melting Point 74 ℃, boiling point 176-177 ℃(2.27kPa), flash point 164 ℃. Soluble in alcohol, ether, acetone, chloroform and acetic acid, water-soluble. Benzaldehyde-like odor, light gradient red. |
Kullanım | Renk aracısı olarak kullanılır |
Risk Kodları | R36/37/38 - Gözleri, solunum sistemini ve cildi rahatsız edici. R52/53 - Su organizmalarına zarar verir, su çevresinde uzun süredir negatif etkiler olabilir. Çek! R22 - Yutulduğunda zararlı R67 - Vapors may cause drowsiness and dizziness R41 - Gözlere ciddi hasar riski R37/38 - Solunum sistemi ve cildi rahatsız edici. R10 - Yanıcı R66 - Repeated exposure may cause skin dryness or cracking R37 - Nefes sistemine iğrençPlease take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML R34 - Yanıklara neden olur R20 - Inhalasyon yoluyla zararlı R20/21/22 - Nefes alınarak, cilt ile temas halinde ve yutularsa zararlı. R36 - Gözleri rahatsız edici R11 - Çok ateşlenebilirPlease take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML |
Güvenlik Açıklaması | S7 - Keep container tightly closed. S16 - Ateşme kaynaklarından uzak tutun. S24/25 Cilt ve gözlerle temas etmekten kaçının. S26 - Gözlerle temas halinde hemen bol miktarda suyla durulayın ve tıbbi tavsiye alın. S61 - Çevre serbest bırakmayı engelleyin.Please take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML Özel talimatlara / güvenlik veri çarşaflara bakın. Çek! S45 - Kaza durumunda veya kendinizi iyi hissetmezseniz, hemen tıbbi tavsiye alın (mümkün olduğunda etiketi gösterin). S39 - Göz/yüz koruması giyin. S36/37/39 Uygun koruyucu giysiler, eldivenler ve göz/yüz koruyucu giyin. S36 - Uygun koruyucu giysiler giyin. |
BM Kimlikleri | UN 2920 8/PG 2 |
WGK Almanya | 1 |
RTECS | CU5775000 |
FLUKA MARKA F KODLARI | 8 |
TSCA'nın | Evet. |
HS Kodu | 29223900 |
Toksiklik | LD50 orally in Rabbit: > 6400 mg/kg |
Zehirli Materiyaler | Acetic acid xylidine mixture of isomers Ammonia Formaldehyde Methenamine |
Referans | 1. Dong Ruizhen, Li Piwu, Shi Feng et al. Effect of glmU gene single function knockout on glucosamine production by Escherichia coli [J]. Chinese brewing 2018 037(004):23-27. 2. Guo Tailin, Kang Tingguo, Zhang Hui. Determination of Saikosaponin in Bupleurum from North to South from Different Producing Areas [J]. Journal of Tianjin University of Traditional Chinese Medicine 2020 v.39(02):107-111. 3. Wang Shupei. Study on the Control Effect and Mechanism of Metschnikowia citriensis of Orange Meiqi Yeast on Postharvest Acid Rot of Citrus Fruits [D]. Southwest University, 2020. |
NIST kimyasal bilgi | Verilen bilgiler: webbook.nist.gov (dış bağlantı) |
EPA kimyasal bilgileri | Tarafından sağlanan bilgiler: ofmpub.epa.gov (dış bağlantı) |
tanıtım | p-dimethylaminobenzaldehyde is an organic intermediate, which can be prepared from N,N-dimethylaniline and DMF. It is reported in the literature that p-dimethylaminobenzaldehyde can be used to prepare high-purity DAST source powder, and can also be used to make a color solution to analyze amino hydroxyurea. |
uygulama | 1. dye intermediates and analytical reagents. The product is used for the determination of indole, skatole, urine blue mother, tryptophan and ergot alkali, etc., and is also used to distinguish serum rash and scarlet fever. 2. In terms of dyes, it can be used to synthesize pressure-sensitive dyes. It is also used in the production of cationic brilliant red G(C.I.BasicRed52). It can also be used as a dye intermediate; used as a reagent for the determination of urobilin, indole, alkaloids, etc. and a chromatographic analysis reagent. 3. Determination of indole, skatole, urine blue mother, tryptophan, albumin, hydrogen peroxide, arsine sodium, o-aminobenzoic acid, antipyrine ergot, etc. It is also used to distinguish serum rash and red fever. 4. Make dyes. 5. Reagents used to detect amino acids, peptides, amines, indole, hydrazine, hydrogen peroxide, anthranilic acid, antipyrine and ergot alkali; used as a chromogenic agent for tryptophan; used to detect tryptophan in protein; used to identify indole-producing microorganisms Test reagents; can react with pyrrole and primary amine to form colored condensation products (Schiff base). |
hazırlık | in a 100ml three-mouth bottle, add 4.9g(0.032mol) of phosphorus oxychloride, slowly add 2.5g(0.031mol) of DMF in an ice bath, finish dropping (8min), stir for 10min, slowly add 3.66g(0.03mol) of N,N-dimethylaniline (10min) to the three-mouth bottle, and finish dropping, move the reaction solution to a boiling water bath for 2 hours. After the reaction, pour the reaction solution into 20ml of ice water, adjust the PH = 4 with 30% sodium hydroxide solution, stand for crystallization, filter the next day to obtain a light yellow or nearly colorless solid, and recrystallize with 30ml of ethanol-water (1:2.5V/V) to obtain the product p-dimethylaminobenzaldehyde. |
kullanılır | dye intermediates and analytical reagents. The product is used for the determination of indole, skatole, urine blue mother, tryptophan and ergot alkali, etc., and is also used to distinguish serum rash and scarlet fever. In terms of dyes, it can be used to synthesize pressure-sensitive dyes. It is also used in the production of cationic brilliant red G(C.I.Basic Red 52). Renk aracısı olarak kullanılır Used as a reagent for the determination of urobilin, indole, alkaloids, etc. and chromatographic analysis reagent Determination of indole, skatole, urine blue mother, tryptophan, Albumin, hydrogen peroxide, arsine sodium, o-aminobenzoic acid, antipyrine ergot alkali, etc., are also used to distinguish serum rash and red fever. Making dyes. Reagents used to detect amino acids, peptides, amines, indole, hydrazine, hydrogen peroxide, anthranilic acid, antipyrine and ergot alkali; used as a chromogenic agent for tryptophan; used to detect tryptophan in protein; test reagents used to identify indole-producing microorganisms; can react with pyrrole and primary amine to form colored condensation products (Schiff base) also known as Euclidean solution/E reagent, mainly used for the identification of Enterobacteriaceae, non-fermenting bacteria, demanding bacteria, and anaerobic bacteria, and the detection of indole derivatives and amines |
üretim yöntemi | using N,N-dimethylaniline as raw material, two methods can be used for production. (1) Methylene-N,N-dimethylaminobenzylamine is generated by the reaction of urotropine, and N,N-dimethylbenzyleneamine is generated by translocation, and then the product is hydrolyzed. (2) Reacts with dimethylformamide in the presence of phosphorus oxychloride. In addition, there is a laboratory preparation method that uses N,N-dimethylaniline, sodium nitrite, and formaldehyde as raw materials. |
spontan yanma sıcaklığı | 445°C |
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