79-37-8 - Names and IdentifiersNameOxalyl chlorideSynonymsOxaloylchlorideOXALYL CHLORIDEOxalyl
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Adı | Oxalyl chloride |
Eşanlamlar | Oxaloylchloride OXALYL CHLORIDE Oxalyl chloride Oxalicdichloride Oxaloyl chloride oxalicdichloride Oxaloyl Chloride Oxalic Dichloride OXALYL DICHLORIDE Oxalyl Dichloride Oxalic dichloride Ethanedioyl Chloride OXALIC ACID CHLORIDE Oxalic Acid Chloride Oxalic Acid Dichloride Ethanedioyl Dichloride OXALIC ACID DICHLORIDE Oxalyl chloride solution 2.0 M in methylene chloride |
CAS'ın | 79-37-8 |
EINECS'in | 201-200-2 |
InChI'nin | InChI=1/C2Cl2O2/c3-1(5)2(4)6 |
InChIKey | CTSLXHKWHWQRSH-UHFFFAOYSA-N |
Moleküler Formül | C2Cl2O2 |
Molar Kütlesi | 126.93 |
Yoğunluk | 1.5 g/mL at 20 °C (lit.) |
Erime noktası | -10--8 °C (lit.) |
Boling Point | 62-65 °C (lit.) |
Flash Point | 176-178°C |
Su Solubility | tepki veriyor |
Buhar Basıncı | 150 mm Hg ( 20 °C) |
Vapor Densitesi | 4.4 (havaya karşı) |
Görüntü | Liquid |
Renk | APHA: 0-150 |
Odor | penetrating odor |
Maruz kalma sınırı | ACGIH: TWA 50 ppmOSHA: TWA 25 ppm; STEL 125 ppmNIOSH: IDLH 2300 ppm |
Merck'ın | 14,6914 |
BRN | 1361988 |
Depolama Koşulları | Store Cold |
Kararlılık | Stable. Incompatible with bases, alcohols, steel, oxidizing agents, alkali metals. Moisture sensitive. Reacts violently with water, liberating toxic gas. |
Hassas | Motor duygusu |
Kırılma Endeksi | n20/D 1.429(lit.) |
Fiziksel ve Kimyasal Özellikler | colored fuming liquid with pungent odor. Water and ethanol can be vigorously decomposed, cooled to -12 deg C that condensed into white crystalline blocks. Decomposition and evolution of carbon monoxide occurred at 60 °c. Soluble in ether, benzene and chloroform, with corrosive and lacrimal. |
Kullanım | Mainly used in the synthesis of pesticides and pesticide intermediates and for the synthesis of other organic chlorides |
Risk Kodları | Please take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML R20 - Inhalasyon yoluyla zararlı R29 - Contact with water liberates toxic gas R34 - Yanıklara neden olur R40 - Kancerogenik etkisinin sınırlı kanıtları R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R37 - Nefes sistemine iğrençPlease take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML R35 - Ciddi yaktırır.Please take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML R23 - Toxic by inhalation |
Güvenlik Açıklaması | S26 - Gözlerle temas halinde hemen bol miktarda suyla durulayın ve tıbbi tavsiye alın. S36/37/39 Uygun koruyucu giysiler, eldivenler ve göz/yüz koruyucu giyin. S43 - Ateş kullanımında... (kullanılacak ateş dövüş ekipmanlarının türüne uyuyor.) S45 - Kaza durumunda veya kendinizi iyi hissetmezseniz, hemen tıbbi tavsiye alın (mümkün olduğunda etiketi gösterin). S8 - Konteyner kuruyu tut. S24/25 Cilt ve gözlerle temas etmekten kaçının. S23 - Buharı nefes almayın. S27 - Hemen bütün kirli giysileri çıkar. |
BM Kimlikleri | UN 2927 6.1/PG 2 |
WGK Almanya | 2 |
RTECS | KI2950000 |
FLUKA MARKA F KODLARI | 9-19-21 |
TSCA'nın | Evet. |
HS Kodu | 29171990 |
Hazır Not | Toxic/Corrosive/Store Cold/Lacrymatory |
Tehlike Sınıfı | 8 |
Paketleme Grubu | II |
Decomposition | 176-178 ºC |
İçeri | oxalyl chloride is a kind of synthetic intermediate of medicine, pesticide, in medicine used as raw materials for the synthesis of antibiotics, in the coating used as raw materials for methacryloylphthalein isocyanate, pesticide industry for the synthesis of ultra-efficient sulfonylurea herbicides benzyl Huanglong, plant growth regulators, etc, it is widely used. |
Kullanım | oxalyl chloride, also known as oxalyl chloride, is an intermediate of benzoylurea insecticides, such as fluifolide, it is also an intermediate of sulfonylurea herbicides such as metsulfuron-methyl, bensulfuron-methyl, pemisulfuron-methyl and the like. In addition, it can also be used in medicine as a raw material for the synthesis of antibiotics. used in the synthesis of organic chlorides. Used as a military gas. commonly used as a military use of toxic gases, but also as a chlorinating agent in organic synthesis for the preparation of organic chlorides mainly used for sulfonylurea herbicides, pesticides, an important raw material for the synthesis of pharmaceutical chemistry intermediates, but also polyamide, Chemical Luminescence agent, high quality acylating agents in chemical industry such as liquid crystals are mainly used for the synthesis of pesticides and pesticide intermediates and for the synthesis of other organic chloride analysis reagents. It is mainly used as an important raw material intermediate for the synthesis of sulfonylurea herbicides, pesticides and medicinal chemistry. It is also a high quality acylating agent in the chemical industry such as polyamide, Chemical Luminescence agent, liquid crystal and other fields. |
üretim yöntemi | prepared by the reaction of anhydrous oxalic acid and phosphorus pentachloride. The preparation method is to obtain oxalyl chloride by reacting oxalic acid with phosphorus pentachloride. The reaction equation is shown in the figure. After phosphorus pentachloride and anhydrous oxalic acid are mixed uniformly, they are slowly heated to about 64 ° C. And reacted until almost no hydrogen chloride is released, and the obtained crude product is further subjected to rectification to obtain oxalyl chloride. |
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