10039-54-0 - Names and IdentifiersNameHydroxylamine sulfateSynonymsHASHydroxylammoniumOxammoniu
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| Adı | Hydroxylamine sulfate |
| Eşanlamlar | HAS Hydroxylammonium Oxammonium sulfate Hydroxyamine sulfate Hydroxylamine sulfate Hydroxylammoniumsulfat Hydroxylamine sulphate Hydroxylammonium sulfate HYDROXYLAMMONIUM SULPHATE bis(hydroxyammonium) sulfate bis(hydroxylammonium) sulphate HYDROXYLAMMONIUM SULFATE REAGENT HYDROXYLAMINESULFATE,CRYSTAL,REAGENT |
| CAS'ın | 10039-54-0 |
| EINECS'in | 233-118-8 |
| InChI'nin | InChI=1/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4) |
| Moleküler Formül | H2O4S.2H3NO |
| Molar Kütlesi | 164.14 |
| Yoğunluk | 1.86 |
| Erime noktası | 170°C (dec.)(lit.) |
| Boling Point | 56.5℃ |
| Su Solubility | 329 g/L (20 ºC) |
| Çözünürlük | water: soluble(lit.) |
| Buhar Basıncı | 0. 001Pa 20°C |
| Görüntü | Crystals |
| Renk | Beyaz |
| Merck'ın | 14,4828 |
| PH | 3.6 (10g/l, H2O, 20℃) |
| Depolama Koşulları | - 20°C |
| Kararlılık | Stability Stable, but may be an explosion hazard - do not heat. May decompose explosively in the presence of alkalies. Air sensitive. Hygroscopic. Incompatible with copper, copper alloys, strong oxidi |
| Hassas | Higroskopik |
| Fiziksel ve Kimyasal Özellikler | Colorless or white crystals. |
| Kullanım | Used as analytical reagents, reducing agents, also used in organic synthesis |
| Risk Kodları | R22 - Yutulduğunda zararlı R36/38 - Irritating to eyes and skin. Please take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML R48/22 - Harmful danger of serious damage to health by prolonged exposure if swallowed. R50 - Su organizmaları için çok toksik.Please take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML R40 - Kancerogenik etkisinin sınırlı kanıtları R21/22 Cilt ile temas halinde ve yutularsa zararlı. R2 - Risk of explosion by shock, friction, fire or other sources of ignition |
| Güvenlik Açıklaması | S22 - Toz nefes almayın. S24 - Avoid contact with skin. S37, uygun eldivenler giyin. S61 - Çevre serbest bırakmayı engelleyin.Please take the official translations! You find them here: http: // europa. eu. int/ eur- lex/ lex/ LexUriServ/ LexUriServ. do? uri=CELEX: 32001L0059: EN: HTML Özel talimatlara / güvenlik veri çarşaflara bakın. Çek! S36/37 Uygun koruyucu giysiler ve eldivenler giyin. |
| BM Kimlikleri | UN 2865 8/PG 3 |
| WGK Almanya | 3 |
| RTECS | NC5425000 |
| FLUKA MARKA F KODLARI | 21 |
| TSCA'nın | Evet. |
| HS Kodu | 28251000 |
| Tehlike Sınıfı | 8 |
| Paketleme Grubu | III |
| Toksiklik | LD50 orally in Rabbit: 842 mg/kg LD50 dermal Rabbit 1500 - 2000 mg/kg |
| Zehirli Materiyaler | Acetoxime Sulfuric acid Ethyl Alcohol |
| Uygulama | mainly used in the preparation of caprolactam and used as pharmaceutical, pesticide intermediates hydroxylamine sulfate, also known as hydroxylamine sulfate, hydrazine sulfate. Its derivatives, oxime or hydroxamic acid derivatives, can be used in the production of insecticides such as methomyl, aldicarb and methomyl, as well as fungicides and herbicides. Hydroxylamine sulfate is a reducing agent, developer and rubber vulcanizing agent, is an important raw material for the synthesis of caprolactam, also used in the production of isoxazole derivatives, sulfanilamide drugs and vitamin B5, vitamin B12, it can also be used for polymer synthesis and chemical analysis. used as a reducing agent, a developer, and a rubber vulcanizing agent. This product is an important raw material for the synthesis of caprolactam. Is also a pharmaceutical, pesticide intermediates, for the production of a series of isoxazole derivatives, sulfa drugs and vitamin B6, B12. Derivatives oxime or hydroxamic acid derivatives can be used to produce pesticides, insecticides, fungicides and herbicides. It can also be used for the purification of polymer synthesis raw materials and compounds, polymerization catalysts and chemical analysis reagents. used as analysis reagent, reducing agent, also used in organic synthesis inorganic analysis reducing agent, can reduce the compound of gold, silver and Mercury into monomer elements, and Fe3, Cu2, v5 is reduced to low-valent compounds, determination of selenium, biological and biochemical studies, photographic developer, manufacture of oxime, Catalyst, swelling agent, polymerization inhibitor of copolymerization reaction, leather hair removal, etc. |
| üretim yöntemi | 1. With methyl ethyl ketone and sulfuric acid and ammonia reaction to produce methyl ethyl ketone oxime, and then with sulfuric acid reaction, through hydrolysis of hydroxylamine sulfate (crystalline) and methyl ethyl ketone and ammonium sulfate by-products. 2. The reaction is carried out by mixing sodium nitrite and ammonium bisulfite, and sulfur dioxide is introduced to absorb the reactant to obtain hydroxylamine disulfonate at low temperature, and then hydrolysis is carried out to obtain hydroxylamine sulfate. Hydroxylamine sulfate can also be obtained by the reaction of sulfuric acid with Nitro hydrocarbon. There are two synthetic methods of hydroxylamine sulfate. Methyl Ethyl Ketone and sulfuric acid are reacted with ammonia to form methyl ethyl ketone oxime, which is then reacted with sulfuric acid to hydrolyze hydroxylamine sulfate. Sodium nitrite and ammonium bisulfite are mixed, and sulfur dioxide is introduced at 0~5 ℃ to absorb and react to obtain hydroxylamine disulfonate, which is hydrolyzed to hydroxylamine sulfate. |
| Kategori | corrosive article |
| zehirli sınıf | zehirlenmek |
| Akut toksisite | abdominal injection-mouse LDL0: 102 mg/kg |
| explosive hazard characteristics | Thermal decomposition |
| yanılabilirlik tehlike özellikleri | flammable; Thermal decomposition of toxic and explosive fumes |
| depolama ve taşıma özellikleri | The warehouse is ventilated and dried at low temperature; It is stored separately from the oxidant |
| Ateş söndürme ajanı | water, sand, dry powder, carbon dioxide |
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